Published January 1991 | Version v1
Journal article Metadata-only

Reactivity of applied and dissolved vanadium(5) complexes during reduction with phosphine

Creators

  • 1. Odesskij Gosudarstvennyj Univ., Odessa (Ukrainian SSR)

Description

The reduction kinetics of vanadium(5) oxygen-containing complexes applied to silica gel with phosphine in the presence of iodide-ions is studied. Protonation and partial kinetic constants characterizing the reaction capability of vanadium(5) complexes are calculated. It is established that oxidation capability of vanadium(5) complexes applied and dissolved increases in VO2+(aq) < VO(OH)2+(aq) < VO3+(aq) series

Additional details

Additional titles

Original title (Russian)
Реакционная способность нанесенных и растворенных комплексов ванадия(5) при восстановлении фосфином

Publishing Information

Journal Title
Kinetika i Kataliz
Journal Volume
32
Journal Issue
1
Series
Kinet. Katal.
Journal Page Range
98-102
ISSN
0453-8811
CODEN
KNKTA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
23000183
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; HYDROXIDES; OXIDES; PERCHLORIC ACID; PHOSPHINES; POTASSIUM IODIDES; REDUCTION; SILICA GEL; VANADIUM COMPLEXES
Descriptors DEC
ADSORBENTS; ALKALI METAL COMPOUNDS; CHALCOGENIDES; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; IODIDES; IODINE COMPOUNDS; KINETICS; MIXTURES; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; POTASSIUM COMPOUNDS; REACTION KINETICS; SOLUTIONS; TRANSITION ELEMENT COMPLEXES