Efficacy of in situ active capping Cd highly contaminated sediments with nano-Fe2O3 modified biochar

Highlights: • BC and nFe₂O₃@BC capping greatly reduced Cd release from sediments. • BC capping was only applicative in alkaline water body. • nFe₂O₃@BC capping availability was affected by disturbance intensity not by pH. • Excessive application of nFe₂O₃@BC capping could increase the risk of Fe release. • Capping layers should be further processed due to most adsorbed Cd was unstabl. Effective remediation of Cd polluted sediment is imperative for its potential damages to aquatic ecosystem. Biochar (BC) and nano-Fe₂O₃ modified BC (nFe₂O₃@BC) were conducted to remedy Cd highly contaminated sediments, and their performances, applicable conditions, and mechanisms were investigated. After 60 d capping, both BC and nFe₂O₃@BC capping inhibited Cd release from sediment to overlying water and porewater (reduction rates >99%). The released Cd concentrations in overlying water with nFe₂O₃@BC capping decreased by 1.6–11.0 times compared to those of BC capping, indicating nFe₂O₃@BC presented a higher capping efficiency. Notably, the increases of acidity and disturbance intensity of overlying water weakened the capping efficiencies of nFe₂O₃@BC and BC. BC capping was inappropriate in acidic and neutral waters (pH 3, 5, and 7) because Cd maintained a continuous release after 15 d, while nFe₂O₃@BC capping was valid in all pH treatments. Under 150 rpm stirring treatment, Cd release rates with BC and nFe₂O₃@BC capping decreased after 15 d and 30 d, respectively. At 0 and 100 rpm treatments, Cd releases treated by nFe₂O₃@BC capping finally kept a balance, indicating nFe₂O₃@BC was valid at low disturbance intensity. BC and nFe₂O₃@BC capping inhibited Cd release via weakening the influences of pH and disturbance on sediment. However, capping layers should be further processed because most adsorbed Cd in capping layers (>98%) would be re-released into overlying water. Meanwhile, excessive application of nFe₂O₃@BC could increase the risk of Fe release. The results provide novel insights into the potential applications of nFe₂O₃@BC and BC in situ capping of Cd polluted sediments in field remediation.