Published February 1983 | Version v1
Journal article Metadata-only

Contribution to the qunatitative analysis of oxide layers formed on high-temperature alloys, using inductively coupled plasma atomic emission spectroscopy. Pt. 2

Creators

  • 1. Bylgarska Akademiya na Naukite, Sofia. Inst. po Obshta i Neorganichna Khimiya
  • 2. Kernforschungsanlage Juelich G.m.b.H. (Germany, F.R.). Inst. fuer Reaktorwerkstoffe und Heisse Zellen
  • 3. Kernforschungsanlage Juelich G.m.b.H. (Germany, F.R.). Zentralabteilung fuer Chemische Analyse

Description

In order to minimize the influence of the composition of the electrolyte on the analytical results the optimum ICP working parameters have been determined. The oxide residue was quantitatively separated from the electrolyte fused with an excess of K2S2O7 and the solution obtained analyzed with ICP. The results are compared with those given by X-ray diffraction. (orig.)

Abstract (German)

Ziel der Arbeit war die quantitative Analyse oxidischer Korrosionsschichten von hochtemperaturstabilen Fe- und Ni-Basislegierungen mit Hilfe des induktiv gekoppelten Plasmas. Hierzu erfolgte zunaechst eine Optimierung der ICP-Arbeitsbedingungen. Dabei wurde insbesondere der Einfluss des Elektrolyten untersucht. Der bei der Elektrolyse erhaltene Oxidrueckstand wurde quantitativ vom Elektrolyten getrennt, mit einem Ueberschuss von K2S2O7 aufgeschlossen und dieLoesung mit Hilfe des ICP analysiert. Die Ergebnisse werden mit den Daten aus der Roentgenbeugung verglichen. (orig.)

Additional details

Additional titles

Subtitle (English)
Optimization of the ICP working parameters and typical analysis of oxide layers

Publishing Information

Journal Title
Fresenius' Z. Anal. Chem.
Journal Volume
314
Journal Issue
3
Series
CODEN: ZACFA.;Fresenius' Z. Anal. Chem.
Journal Page Range
356-361
ISSN
0372-7920

Conference

Title
Workshop on applied surface analysis.
Dates
11-14 May 1982.
Place
Juelich (Germany, F.R.).

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
14774779
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ATOMIZATION; CARRIERS; CORROSION PRODUCTS; ELECTROLYTES; EMISSION SPECTROSCOPY; FLOW RATE; GASES; HEAT RESISTING ALLOYS; HIGH-FREQUENCY DISCHARGES; INCOLOY 800H; IRON BASE ALLOYS; MULTI-ELEMENT ANALYSIS; OPTIMIZATION; OXIDES; QUANTITATIVE CHEMICAL ANALYSIS; VISCOSITY; X-RAY DIFFRACTION
Descriptors DEC
ALLOYS; ALUMINIUM ADDITIONS; CHALCOGENIDES; CHEMICAL ANALYSIS; CHROMIUM ALLOYS; COHERENT SCATTERING; DIFFRACTION; ELECTRIC DISCHARGES; FLUIDS; INCOLOY ALLOYS; IRON ALLOYS; MANGANESE ADDITIONS; NICKEL ALLOYS; OXYGEN COMPOUNDS; SCATTERING; SILICON ADDITIONS; SPECTROSCOPY; TITANIUM ADDITIONS; TRANSITION ELEMENT ALLOYS