Published February 1979 | Version v1
Journal article

Investigation of different-ligand complexes of holmium and erbium with NTA and carbonate ion

  • 1. AN Ukrainskoj SSR, Kiev. Inst. Fizicheskoj Khimii

Description

Found out have been the optimum conditions for the formation of the lantanides (Ln) multiligand complexes with the nitriletriacetic acid (NTA) and the carbonate-ion. It has been established that the components correlation in complex compounds is equal to 1:1:1. Computed have been the values of the oscillator forces of the absorption bands, that conform to the ''supersensitive'' migration of the multiligand complexes, It is shown that the increment in the oscillator forces, the induced entering of one carbonate-ion into the Ln-NTA complex molecule conforms to about 1/4 of the oscillator forces increment during the migration from the aquo ion to the [Ln(CO3)4]5- complex carbonaceous ion

Additional details

Additional titles

Original title (Russian)
Исследование разнолигандных комплексов гольмия и эрбия с нитрилотриуксусной кислотой и карбонат-ионом

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
24
Journal Issue
2
Series
Zh. Neorg. Khim.
Journal Page Range
331-334
ISSN
0044-457X

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).