Spectral analysis for systems of atoms and molecules coupled to the quantized radiation field
Creators
- 1. Technische Univ. Berlin (Germany). Fachbereich 3 - Mathematik
- 2. Institut fuer Theoretische Physik, ETH Hoenggerberg, 8093 Zuerich (Switzerland)
- 3. Department of Mathematics, University of Toronto, Toronto, M5S 3G3 (Canada)
Description
We consider systems of static nuclei and electrons - atoms and molecules - coupled to the quantized radiation field. The interactions between electrons and the soft modes of the quantized electromagnetic field are described by minimal coupling, p→p-eA(x), where A(x) is the electromagnetic vector potential with an ultraviolet cutoff. If the interactions between the electrons and the quantized radiation field are turned off, the atom or molecule is assumed to have at least one bound state. We prove that, for sufficiently small values of the fine structure constant α, the interacting system has a ground state corresponding to the bottom of its energy spectrum. For an atom, we prove that its excited states above the ground state turn into metastable states whose life-times we estimate. Furthermore the energy spectrum is absolutely continuous, except, perhaps,in a small interval above the ground state energy and around the threshold energies of the atom or molecule. (orig.)
Additional details
Publishing Information
- Journal Title
- Communications in Mathematical Physics
- Journal Volume
- 207
- Journal Issue
- 2
- Journal Page Range
- p. 249-290
- ISSN
- 0010-3616
- CODEN
- CMPHAY
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 31000324
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ATOMS; BOUND STATE; EIGENVALUES; ELECTROMAGNETIC FIELDS; ELECTROMAGNETIC RADIATION; ELECTRONIC STRUCTURE; ENERGY SPECTRA; GROUND STATES; HAMILTONIANS; LIFETIME; METASTABLE STATES; MOLECULES; QUANTUM ELECTRODYNAMICS; RESONANCE
- Descriptors DEC
- ELECTRODYNAMICS; ENERGY LEVELS; EXCITED STATES; FIELD THEORIES; MATHEMATICAL OPERATORS; QUANTUM FIELD THEORY; QUANTUM OPERATORS; RADIATIONS; SPECTRA
Optional Information
- Notes
- With 5 figs., 36 refs.