Published 1996
| Version v1
Journal article
Synthesis of mono-, di-, tri-, and tetraethyl-o-carboranes by electrophilic alkylation of o-carborane with ethyl bromide in the presence of AlCl3 and their transformations
- 1. AN SSSR, Moscow (Russian Federation). Inst. Ehlementoorganicheskikh Soedinenij
- 2. AN SSSR, Moscow (Russian Federation). Inst. Organicheskoj Khimii
- 3. AN SSSR, Moscow (Russian Federation). Matematicheskij Inst.
Description
Optimal conditions for preparation of 9-ethyl-, 9,12-diethyl, 8,9,12-triethyl- and 8,9,10,12-tetraethyl-o-carboranes under the action of EtBr on o-carborane in the presence of AlCl3 were determined. The behavior of these o-carborane derivatives with respect to electrophilic and nucleophilic reagents was studied. 17 refs.; 3 tabs
Additional details
Additional titles
- Original title (Russian)
- Получение моно-, ди-, три- и тетраэтил-о-карборанов электрофильным алкилированием щ-карборана этилбромидолм в присуцтвии хлористого алюминиы а и некоторые их превращения
Publishing Information
- Journal Title
- Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
- Journal Issue
- no.11
- Journal Page Range
- p. 2755-2763.
- ISSN
- 1026-3500
- CODEN
- IASKEA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 28033075
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALKYLATION; CARBORANES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CHEMICAL REACTIONS; LITHIUM COMPOUNDS; NMR SPECTRA; ORGANOMETALLIC COMPOUNDS; PROTONS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; BARYONS; CATIONS; CHARGED PARTICLES; ELEMENTARY PARTICLES; FERMIONS; HADRONS; HYDROGEN IONS; HYDROGEN IONS 1 PLUS; IONS; NUCLEONS; ORGANIC BORON COMPOUNDS; ORGANIC COMPOUNDS; SPECTRA; SYNTHESIS; YIELDS