Published 1985
| Version v1
Journal article
An exciton approach to the excited states of two electron atoms. II Determination of spectroscopic parameters, polarizabilites and dispersion coefficients of H-, He, Li+, Be2+ and Ne8+
Description
The exciton model is applied quantitatively to a description of the excited states of representative members of the helium isoelectronic series; viz. H+, He, Li+, Be2+ and Ne8+. The energies of the eight lowest excited states are in good agreement with experiment, for a relatively small (1s-4p) hydrogenic basis; the ground state is obtained with slightly less precision. Response properties including oscillator strengths, polarizabilites and dispersion interaction coefficients are also calculated. The method leads to particularly simple interpretations of the wave functions and the energies
Additional details
Publishing Information
- Journal Title
- Aust. J. Chem.
- Journal Volume
- 38
- Journal Issue
- 1
- Series
- Aust. J. Chem.
- Journal Page Range
- 11-21
- ISSN
- 0004-9425
INIS
- Country of Publication
- Australia
- Country of Input or Organization
- Australia
- INIS RN
- 16047275
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- BERYLLIUM IONS; DISPERSION RELATIONS; EXCITED STATES; EXCITON MODEL; GROUND STATES; HELIUM; HYDROGEN IONS 1 PLUS; ISOELECTRONIC ATOMS; LITHIUM IONS; NEON IONS; OSCILLATOR STRENGTHS; POLARIZABILITY; WAVE FUNCTIONS
- Descriptors DEC
- ATOMIC IONS; ATOMS; CATIONS; CHARGED PARTICLES; ELECTRICAL PROPERTIES; ELEMENTS; ENERGY LEVELS; FUNCTIONS; HYDROGEN IONS; IONS; MATHEMATICAL MODELS; NONMETALS; NUCLEAR MODELS; PHYSICAL PROPERTIES; RARE GASES