Published February 2003 | Version v1
Journal article Metadata-only

Synthesis and crystal structure of the new lead borophosphate Pb2[BP2O8(OH)]

Creators

  • 1. Moskovskij Gosudarstvennyj Univ. im. M.V. Lomonosova, Moscow (Russian Federation)

Description

By the method of hydrothermal synthesis crystals of the new lead borophosphate Pb2[BP2O8(OH)] are prepared. The structure is determined without knowledge of chemical formulae by the heavy atom method: a=5.695(8), b=16.05(4), c=8.064(9) A, γ=94.77(4) Deg, sp.gr. P21/n. Anionic radical is represented by [BP2O8(OH)]4- tape drawn along axe c and composed by the way of condensation of block-groups of four tetrahedrons: central boron one and three end phosphorus ones. Formation of the new structure is related with presence of H+ ions in solution that leads to protonation of the one of oxygen atoms of B-tetrahedron of anionic radical

Abstract (Russian)

Методом гидротермального синтеза получены кристаллы нового борофосфата свинца Pb2[BP2O8(OH)]. Структура определена без знания химической формулы методом тяжелого атома: a=5.695(8), b=16.05(4), c=8.064(9) A, γ=94.77(4) град, пр.гр. P21/n. Анионный радикал представлен лентой [BP2O8(OH)]4-, вытянутой вдоль оси c и составленной путем конденсации блоков-группировок из четверок тетраэдров: центрального борного и трех концевых фосфорных. Образование новой структуры связано с присутствием в растворе ионов H+, что приводит к протонизации одного из атомов кислорода B-тетраэдра анионного радикала

Additional details

Additional titles

Original title (Russian)
Синтез и кристаллическая структура нового борофосфата свинца Пб

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
48
Journal Issue
2
Journal Page Range
p. 204-207
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
35021978
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BORON COMPOUNDS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CRYSTAL LATTICES; HYDROGEN COMPOUNDS; INTERATOMIC DISTANCES; LATTICE PARAMETERS; LEAD COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; SPACE GROUPS
Descriptors DEC
CRYSTAL STRUCTURE; DISTANCE; SYMMETRY GROUPS; SYNTHESIS

Optional Information

Notes
8 refs.; 3 tabs.; 2 figs.