Published December 1, 2005
| Version v1
Journal article
Photoinduced ion-pair formation in the (HI)m(H2O)n cluster system
- 1. Departments of Chemistry and Physics, Pennsylvania State University, University Park, Pennsylvania 16802 (United States)
Description
The temporal behavior of the photoinduced ion-pair formation process in the (HI)m(H2O)n (n=1-6 for m=1 and n=1-4 for m=2) cluster system has been studied via the coupling between the g 3Σ- Rydberg and V 1Σ+ valence states. Comparison of the time constants obtained to those measured in previous experiments for the analogous process in HBr-water clusters, along with a detailed analysis of the signal intensity as a function of laser-pulse power, provides new insight into and confirmation of the previously proposed ion-pair formation mechanism
Additional details
Identifiers
- DOI
- 10.1063/1.2135291;
Publishing Information
- Journal Title
- Journal of Chemical Physics
- Journal Volume
- 123
- Journal Issue
- 21
- Journal Page Range
- p. 214308-214308.8
- ISSN
- 0021-9606
- CODEN
- JCPSA6
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 37035766
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- COUPLING; HYDROBROMIC ACID; ION PAIRS; MOLECULAR CLUSTERS; PHOTOCHEMISTRY; PHOTON-MOLECULE COLLISIONS; RYDBERG STATES; SOLVATION; VALENCE; WATER
- Descriptors DEC
- BROMINE COMPOUNDS; CHEMISTRY; COLLISIONS; ENERGY LEVELS; EXCITED STATES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; MOLECULE COLLISIONS; OXYGEN COMPOUNDS; PHOTON COLLISIONS
Optional Information
- Notes
- (c) 2005 American Institute of Physics