Published January 2006 | Version v1
Journal article Metadata-only

The synthesis and crystal structure of mixed-cation salt of ruthenium(II) trans-hydroxotetranitronitrosocomplex, KNa[Ru(NO)(NO2)4(OH)]·H2O

Creators

  • 1. SO RAN, Inst. Neorganicheskoj Khimii im. A.V. Nikolaeva, Novosibirsk (Russian Federation)

Description

Mixed-cation complex salt KNa[Ru(NO)(NO2)4(OH)]·H2O is synthesized and investigated by the methods of IR spectroscopy, X-ray diffraction and X-ray structural analyses. Lattice parameters are: a=7.389(1), b=14.196(2), c=21.507(5) A, V=2256.0(7) A3, Z=8, space group - P212121. Structure is chiral, absolute structural parameter is 0.04. By the method of transmission sublattice the common motive of complex anions disposition in the structure is determined. Geometric characteristics of coordinated NO2-groups are analyzed

Abstract (Russian)

Синтезирована и исследована методами ИК спектроскопии, рентгенофазового и рентгеноструктурного анализов смешанная по катионам комплексная соль KNa[Ru(NO)(NO2)4(OH)]·H2O. Кристаллографические данные представлены: a=7.389(1), b=14.196(2), c=21.507(5) A, V=2256.0(7) A3, Z=8, пр. гр. - P212121. Структура хиральная, абсолютный структурный параметр - 0.04. Методом трансляционной подрешетки определен общий мотив расположения комплексных анионов в структуре. Проанализированы геометрические характеристики координированных NO2-групп

Additional details

Additional titles

Original title (Russian)
Синтез и кристаллическая структура смешанной по катионам соли транс-гидроксотетранитронитрозокимплекса рутения(II) KNa[Ру(NO)(NO

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
47
Journal Issue
1
Journal Page Range
p. 69-76
ISSN
0136-7463
CODEN
ZSTKAI

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
37064584
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL PREPARATION; CRYSTAL LATTICES; HYDRATES; LATTICE PARAMETERS; MOLECULAR BEAM EPITAXY; MOLECULAR STRUCTURE; NITRO COMPOUNDS; NITROSO COMPOUNDS; POTASSIUM COMPOUNDS; RUTHENIUM COMPLEXES; SODIUM COMPOUNDS; SPACE GROUPS
Descriptors DEC
ALKALI METAL COMPOUNDS; COMPLEXES; CRYSTAL GROWTH METHODS; CRYSTAL STRUCTURE; EPITAXY; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SYMMETRY GROUPS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
28 refs., 3 figs., 2 tabs.