Published June 1, 2009
| Version v1
Journal article
Promising Ni-Fe-LSGMC anode compatible with lanthanum gallate electrolyte
Creators
- 1. School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332-0245 (United States)
- 2. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)
Description
A number of composite materials in the Ni-Fe-LSGMC family have been studied as potential anodes for solid oxide fuel cells (SOFCs) based on strontium, magnesium, and cobalt doped lanthanum gallate electrolyte (LSGMC). The results show that Ni reacts with LSGMC especially under reducing conditions at high temperatures, resulting in high contact resistance, large electrode polarization, and poor performance. The reaction between Ni and LSGMC depends strongly on the composition and pre-sintering temperature of LSGMC, the concentration of iron in the electrode, and the processing and operating temperatures. Under proper conditions, Ni-Fe-LSGMC5 could be a promising high-performance anode with good compatibility with LSGMC5 electrolyte.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.electacta.2009.02.002Additional details
Identifiers
- DOI
- 10.1016/j.electacta.2009.02.002;
- PII
- S0013-4686(09)00224-2;
Publishing Information
- Journal Title
- Electrochimica Acta
- Journal Volume
- 54
- Journal Issue
- 15
- Journal Page Range
- p. 3872-3876
- ISSN
- 0013-4686
- CODEN
- ELCAAV
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 41044106
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ANODES; COBALT; COMPOSITE MATERIALS; DOPED MATERIALS; ELECTROLYTES; GALLIUM COMPOUNDS; IRON; LANTHANUM COMPOUNDS; MAGNESIUM; NICKEL; OXYGEN COMPOUNDS; SINTERING; SOLID OXIDE FUEL CELLS; STRONTIUM
- Descriptors DEC
- ALKALINE EARTH METALS; DIRECT ENERGY CONVERTERS; ELECTROCHEMICAL CELLS; ELECTRODES; ELEMENTS; FABRICATION; FUEL CELLS; HIGH-TEMPERATURE FUEL CELLS; MATERIALS; METALS; RARE EARTH COMPOUNDS; SOLID ELECTROLYTE FUEL CELLS; TRANSITION ELEMENTS
Optional Information
- Copyright
- Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.