Published 1994 | Version v1
Journal article Metadata-only

Oxidation by a reagent H2O2-vanadium complex-pyrazine-2-carboxylic acid. 3. Evidence for hydroxyl radical formation

Creators

  • 1. AN SSSR, Moscow (Russian Federation). Inst. Khimicheskoj Fiziki

Description

Evidence for the formation of hydroxyl radicals and their participation in the hydrocarbon oxidation by a reagent H2O2-vanadium complex-pyrazine-2-carboxylic acid has been obtained by two different routes: by the application of spin trapping and kinetically by the competitive oxidation of a mixture benzene-aliphatic alcohol. The suggestion has been made that the hydroxyl radicals generate in the reaction of vanadium complex (Bu4N)VO3 with hydrogen peroxide. 22 refs.; 1 fig

Additional details

Additional titles

Original title (Russian)
Окисление реагентом Н

Publishing Information

Journal Title
Izvestiya Akademii Nauk. Seriya Khimicheskaya
Journal Issue
no.7
Journal Page Range
p. 1212-1214.
ISSN
0002-3353
CODEN
IASKEA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
27050141
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CARBOXYLIC ACIDS; CHEMICAL REACTION KINETICS; HYDROCARBONS; HYDROGEN PEROXIDE; HYDROXYL RADICALS; OXIDATION; QUATERNARY COMPOUNDS; REACTION INTERMEDIATES; VANADIUM COMPLEXES
Descriptors DEC
AMINES; CHEMICAL REACTIONS; COMPLEXES; HYDROGEN COMPOUNDS; KINETICS; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PEROXIDES; RADICALS; REACTION KINETICS; TRANSITION ELEMENT COMPLEXES