Published October 1985
| Version v1
Journal article
Influence of the nature of the oxidizing agents on the mechanism of the oxidation of carbon monoxide in the presence of an aqua complex of palladium (II)
- 1. Institute of Catalysis, Acad. of Sci., Novosibirsk
Description
The kinetics of the oxidation of CO in the presence of an aqua complex of Pd(II) by VO+2 and Fe(III) ions and by heteropolyacids (HPA) viz., H3PMo12O40,H4PMo11 VO40, and H4PW11VO40, was studied. A comparison of the data obtained with the results of the oxidation of CO by strong oxidizing agents - Cr2O72- and Ce(IV) ions - made it possible to conclude that rapid occurrence of the reaction requires an optimum potential of the oxidizing agent 0.7 < E < 1 V. This confirms the assumption that the intermediate carbonyl complexes of partially reduced palladium are the most active in this reaction
Additional details
Publishing Information
- Journal Title
- Kinet. Catal. (Engl. Transl.)
- Journal Volume
- 26
- Journal Issue
- 2,PT.2
- Series
- Kinet. Catal. (Engl. Transl.).
- Journal Page Range
- 404-408
- ISSN
- 0023-1584
- CODEN
- KICAA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 18031717
- Subject category
- S61: RADIATION PROTECTION AND DOSIMETRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AIR POLLUTION; CARBON MONOXIDE; CATALYSIS; CERIUM COMPOUNDS; CHEMICAL REACTION KINETICS; CHROMATES; IRON COMPOUNDS; MOLYBDOPHOSPHORIC ACID; OXIDATION; OXIDIZERS; PALLADIUM COMPLEXES; POLLUTION ABATEMENT; REDOX POTENTIAL; TUNGSTOPHOSPHORIC ACID; VANADATES
- Descriptors DEC
- CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL REACTIONS; CHROMIUM COMPOUNDS; COMPLEXES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; KINETICS; MOLYBDENUM COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; POLLUTION; RARE EARTH COMPOUNDS; REACTION KINETICS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS; TUNGSTEN COMPOUNDS; VANADIUM COMPOUNDS
Optional Information
- Notes
- Cover-to-cover translation of Kinetika i Kataliz (USSR).