Published December 15, 1998
| Version v1
Journal article
Synthesis and NMR studies of methyl 3-O-[(R)- and (S)-1-carboxyethyl]-α-d-gluco-, galacto- and manno- pyranosides
Creators
- 1. Department of Chemistry, Swedish University of Agricultural Sciences, P.O. Box 7015, SE-750 07 Uppsala (Sweden)
Description
The title compounds were prepared by condensation of a suitably protected monosaccharide and (R)- or (S)-2-chloropropionic acid followed by removal of the protecting groups. Characterisation by 1H and 13C NMR spectroscopy and NOE difference experiments revealed both chemical shift and enhancement differences between the diastereomers which could be used in determination of the absolute configuration of the 1-carboxyethyl group. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)
Additional details
Publishing Information
- Journal Title
- Carbohydrate Research
- Journal Volume
- 313
- Journal Issue
- 3-4
- Journal Page Range
- p. 157-164
- ISSN
- 0008-6215
- CODEN
- CRBRAT
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 43122167
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL SHIFT; MOLECULAR STRUCTURE; MONOSACCHARIDES; NUCLEAR MAGNETIC RESONANCE; STRUCTURAL CHEMICAL ANALYSIS
- Descriptors DEC
- CARBOHYDRATES; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; RESONANCE; SACCHARIDES
Optional Information
- Notes
- This record replaces 31061629