Published December 2019 | Version v1
Book

Intriguing modulations in the tautomerization of chrysazine assisted by host-guest interactions

  • 1. Radiation and Photochemistry Division, Bhabha Atomic Research Centre, Mumbai (India)
  • 2. Analytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai (India)

Description

The present study explores the interesting effect of p-sulfonatocalix(n)arene(SCXn) and cyclodextrin (CD) hosts on the excited-state intramolecular proton transfer (ESIPT) process of Chrysazine (CZ), a model anti tumour drug. The facile ESIPT process of CZ is considerably inhibited when the dye is bound to SCXn hosts. In spite of lower binding affinity, the effect is interestingly more profound with SCX6 than SCX4. For CD-CZ systems, the ESIPT process is hindered in the presence of β-CD while it remains unaffected in the presence of γCD. (author)

Part of:
Proceedings of the fifteenth DAE-BRNS biennial Trombay symposium on radiation and photochemistry: book of abstract

Additional details

Publishing Information

Publisher
Bhabha Atomic Research Centre
Imprint Place
Mumbai (India)
ISBN
978-81-940321-5-1
Imprint Title
Proceedings of the fifteenth DAE-BRNS biennial Trombay symposium on radiation and photochemistry: book of abstract
Imprint Pagination
184 p.
Journal Page Range
p. 75

Conference

Title
15. DAE-BRNS biennial Trombay symposium on radiation and photochemistry
Acronym
TSRP-2020
Dates
5-9 Jan 2020
Place
Mumbai (India)

INIS

Country of Publication
India
Country of Input or Organization
India
INIS RN
54095237
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
AROMATICS; EXCITED STATES; ISOMERIZATION; NEOPLASMS; PROTONS
Descriptors DEC
BARYONS; CHEMICAL REACTIONS; DISEASES; ELEMENTARY PARTICLES; ENERGY LEVELS; FERMIONS; HADRONS; HYDROCARBONS; NUCLEONS; ORGANIC COMPOUNDS

Optional Information