Published June 1976
| Version v1
Journal article
On alkali metal suboxides. 8
- 1. Max-Planck-Institut fuer Festkoerperforschung, Stuttgart (Germany F.R.)
Description
Preparation and crystal growth of the hardly accessible compound Cs4O are described. A single crystal investigation at -300C leads to a structure corresponding to the formula [Cs11O3]Cs. Clusters of the composition Cs11O3, which are characteristic for caesium suboxides form a hcp arrangement, the single caesium atoms occupying the quasi-octahedral sites of this arrangement as in the case of NiAs. (author)
Abstract (German)
Darstellung und Einkristallzüchtung der schwer zugänglichen Verbindung Cs 4 O werden beschrieben. Die bei −30°C durchgeführte Strukturuntersuchung ergibt einen Aufbau gemäß der Formel [Cs 11 O 3 ]Cs. Die für Cäsiumsuboxide charakteristischen Cs 11 O 3 ‐Gruppen bilden eine hexagonal dichte Anordnung, in der die einzelnen metallisch gebunden Cäsiumatome quasi Oktaederlücken nach Art des NiAs‐Typs besetzen.Additional details
Additional titles
- Subtitle (English)
- Studies on the structure of Cs_4O
- Original title (German)
- Ueber Alkalimetallsuboxide. 8
- Original subtitle (German)
- Untersuchungen zum Aufbau von Tetracaesiumoxid.
Identifiers
Publishing Information
- Journal Title
- Zeitschrift für anorganische und allgemeine Chemie
- Journal Volume
- 423
- Journal Issue
- 3
- Series
- Z. Anorg. Allg. Chem.
- Journal Page Range
- 203-211
- ISSN
- 0044-2313
INIS
- Country of Publication
- German Democratic Republic
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 7272455
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CESIUM OXIDES; CHEMICAL PREPARATION; CRYSTAL GROWTH; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MONOCRYSTALS; STRUCTURAL CHEMICAL ANALYSIS; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CESIUM COMPOUNDS; CHALCOGENIDES; COHERENT SCATTERING; CRYSTALS; DIFFRACTION; DISTANCE; OXIDES; OXYGEN COMPOUNDS; SCATTERING; SYNTHESIS
Optional Information
- Notes
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