Published July 15, 1981
| Version v1
Journal article
Tritium isotope fractionation between hydrogen sulphide and methyl thiol
Description
Tritium isotope effect in the gas phase exchange reaction between hydrogen sulphide and methyl thiol has been determined. The results obtained vary from 1.08 to 1.04 over the temperature range of 283-323 K. The calculations based upon the quantum statistical theory of the isotope effects agree well with the experimental results. (author)
Additional details
Publishing Information
- Journal Title
- Radiochem. Radioanal. Lett.
- Journal Volume
- 48
- Journal Issue
- 3-4
- Series
- Radiochem. Radioanal. Lett.
- Journal Page Range
- 193-199
- ISSN
- 0079-9483
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 13658600
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL REACTION KINETICS; EQUILIBRIUM; HYDROGEN SULFIDES; ISOTOPE EFFECTS; ISOTOPIC EXCHANGE; LABELLED COMPOUNDS; MEDIUM TEMPERATURE; TEMPERATURE DEPENDENCE; THIOLS; TRITIUM
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHALCOGENIDES; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; RADIOISOTOPES; REACTION KINETICS; SULFIDES; SULFUR COMPOUNDS; YEARS LIVING RADIOISOTOPES
Optional Information
- Notes
- 13 refs.