Published September 2007 | Version v1
Journal article Metadata-only

A study of the optical and EPR spectra for Ni2+ ion at the Cd2+(II) site of CsCdCl3 crystal

Creators

  • 1. Department of Applied Physics, Chongqing Institute of Technology, Chongqing 400050 (China)
  • 2. Department of Material Science, Sichuan University, Chengdu 610064 (China)
  • 3. International Centre for Materials Physics, Chinese Academy of Sciences, Shengyang 110016 (China)
  • 4. Department of Physics, Civil Aviation Flying Institute of China, Guanghan 618307 (China)

Description

The optical absorption bands and spin-Hamiltonian parameters (g -factors g parallel, g perpendicularto and zero-field splitting D measured by EPR spectra) of Ni2+ ion at the Cd2+ (II) site of CsCdCl3 crystals are calculated by using the method of diagonalizing the complete energy matrix of 3d8 ions in trigonal symmetry. The calculated results are in reasonable agreement with the observed values. The defect structure of this Ni2+ impurity center is also estimated from the calculations. The results are discussed. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Availability note (English)

Available from: http://dx.doi.org/10.1002/pssb.200743046

Additional details

Identifiers

DOI
10.1002/pssb.200743046;

Publishing Information

Journal Title
Physica Status Solidi. B, Basic Research
Journal Volume
244
Journal Issue
9
Journal Page Range
p. 3308-3312
ISSN
0370-1972
CODEN
PSSBBD

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
38091260
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ABSORPTION SPECTRA; CADMIUM CHLORIDES; CESIUM CHLORIDES; CRYSTAL DEFECTS; CRYSTALS; CUBIC LATTICES; DOPED MATERIALS; EIGENVALUES; ELECTRON SPIN RESONANCE; ENERGY-LEVEL TRANSITIONS; EXCITED STATES; HAMILTONIANS; LANDE FACTOR; NICKEL ADDITIONS; NICKEL IONS; SPIN ORIENTATION; THEORETICAL DATA; VISIBLE SPECTRA
Descriptors DEC
ALKALI METAL COMPOUNDS; ALLOYS; CADMIUM COMPOUNDS; CADMIUM HALIDES; CESIUM COMPOUNDS; CHARGED PARTICLES; CHLORIDES; CHLORINE COMPOUNDS; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DATA; DIMENSIONLESS NUMBERS; ENERGY LEVELS; HALIDES; HALOGEN COMPOUNDS; INFORMATION; IONS; MAGNETIC RESONANCE; MATERIALS; MATHEMATICAL OPERATORS; NICKEL ALLOYS; NUMERICAL DATA; ORIENTATION; QUANTUM OPERATORS; RESONANCE; SPECTRA; TRANSITION ELEMENT ALLOYS

Optional Information

Notes
With 2 tabs., 30 refs.. SICI: 0370-1972(200709)244:9<3308::AID-PSSB200743046>3.0.TX;2-7