Published May 1975 | Version v1
Journal article

Investigation of ZnI2-KI-C3H7NO system by ultrasonic method

  • 1. Kievskij Gosudarstvennyj Univ. (Ukrainian SSR)
  • 2. Ukrainskaya Sel'skokhozyajstvennaya Akademiya, Kiev

Description

Applicability of the ultrasonic impulses for the research of complex formation in the solutions was demonstrated using ZnI2-KI-C3H7NO system as an example. Changing the solvent structure during complexing was studied. It was determined that ion solvation numbers reflect electrostriction influence of ions on the surrounding solvent moleculas. The maximum effect on dimethylformamide (C3H7NO) was made by the complex compound KZnI3 acting as destrictor and the sound speed decrease was the highest in its solution. Possibility of using adiabatic compressibility of the solutions for complexing studies is analysed

Additional details

Additional titles

Original title (Russian)
Исследование системы ZnI

Publishing Information

Journal Title
Zh. Obshch. Khim.
Journal Volume
45
Journal Issue
5
Series
Zh. Obshch. Khim.
Journal Page Range
977-979

Optional Information

Notes
For English translation see the journal J. Gen. Chem. USSR.