Published January 1993 | Version v1
Journal article Metadata-only

Cupra-decaborates of alkali metals and alkylammonium

Creators

  • 1. AN SSSR, Moscow (Russian Federation). Inst. Obshchej i Neorganicheskoj Khimii

Description

Cupra-decaborates of alkali metals and alkylammonium were synthesized and characterized by the methods of magnetic susceptibility, IR and electron spectroscopy. It is shown that cations of copper(1) and alkylammonium interact with closo-decaborate anion as a result of formation of identical type of local bonds E...B and E...H-B, where E = Cu+, N, the strength of which being commensurable. In electron absorption spectra bands of charge transfer between closo-decaborate anion and copper(1) cation are observed. Stability of the compounds in the air during heating was considered

Additional details

Additional titles

Original title (Russian)
Купра-декабораты щелочных металлов и алкиламмония

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
38
Journal Issue
1
Journal Page Range
p. 38-41.
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
25000143
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; AMMONIUM COMPOUNDS; BOROHYDRIDES; CESIUM COMPOUNDS; CHEMICAL BONDS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; COPPER COMPLEXES; INFRARED SPECTRA; MAGNETIC SUSCEPTIBILITY; POTASSIUM COMPOUNDS; QUATERNARY COMPOUNDS; STABILITY
Descriptors DEC
ALKALI METAL COMPOUNDS; AMINES; BORON COMPOUNDS; COMPLEXES; HYDROGEN COMPOUNDS; MAGNETIC PROPERTIES; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES