Self-ignition risk classification for coal dust layers of three coal types on a hot surface
- 1. Inspection and Research Institute of Boiler and Pressure Vessel, Dalian, Liaoning, 116000 (China)
- 2. School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning, 116024 (China)
- 3. School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 (China)
- 4. Department of Safety, Health, and Environmental Engineering, National Yunlin University of Science and Technology, Douliu, Yunlin, 64002, Taiwan, ROC (China)
Description
H I G H L I G H T S• Thermal combustibility and susceptibility for coal dust were investigated. • Chemical reaction mode regulated the temperature after thermal runaway. • Thermokinetic parameters were measured and calculated by TGA and hot surface test. • Self-ignition risk of samples was determined using modified risk matrix method. Pulverised coal in industrial sites and their dust can experience spontaneous combustion and self-heating, increasing the risk of fire and dust explosion. The main objective of the present study was to resolve thermal combustibility (as reflected by comprehensive combustibility index [Sn] and kinetic properties) for three types of coal (S1-BN, S2-CY, and S3-JM) through thermal analysis. The Sn values of the samples indicated a degradation in the quality of comprehensive combustibility. Apparent activation energies (Ea) at the initial stage of spontaneous coal combustion (130–300 °C) were decided through Achar and Coats–Redfern methods. Moreover, thermal susceptibility (minimum auto-ignition temperature [MAIT] and thermodynamic parameters) was evaluated using the hot plate method. The MAIT values for the three coal dust layers were 210, 220, and 300 °C. The results exhibited that heat conduction was the dominant heat transfer mode that originated the temperature distribution within the coal dust layer under the subcritical conditions for ignition; while it converted chemical reaction controlled-mode after thermal runaway. Furthermore, the results based on an improved risk matrix approach showed the S1-BN and S2-CY samples had a high self-ignition risk, whereas the S3-JM sample had a moderate ignition risk.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.energy.2020.119197Additional details
Identifiers
- DOI
- 10.1016/j.energy.2020.119197;
- PII
- S0360544220323045;
Publishing Information
- Journal Title
- Energy (Oxford)
- Journal Volume
- 216
- Journal Page Range
- vp.
- ISSN
- 0360-5442
- CODEN
- ENEYDS
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 54006409
- Subject category
- S01: COAL, LIGNITE, AND PEAT; S42: ENGINEERING;
- Descriptors DEI
- ACTIVATION ENERGY; CLASSIFICATION; COAL; HEATING; IGNITION; KINETICS; MATRICES; SPONTANEOUS COMBUSTION; TEMPERATURE DISTRIBUTION; THERMAL CONDUCTION; THERMAL GRAVIMETRIC ANALYSIS; THERMODYNAMICS
- Descriptors DEC
- CARBONACEOUS MATERIALS; CHEMICAL ANALYSIS; CHEMICAL REACTIONS; COMBUSTION; ENERGY; ENERGY SOURCES; ENERGY TRANSFER; FOSSIL FUELS; FUELS; GRAVIMETRIC ANALYSIS; HEAT TRANSFER; MATERIALS; OXIDATION; QUANTITATIVE CHEMICAL ANALYSIS; THERMAL ANALYSIS; THERMOCHEMICAL PROCESSES
Optional Information
- Copyright
- Copyright (c) 2020 Elsevier Ltd. All rights reserved.