Published March 15, 1987
| Version v1
Journal article
Muonic alkyl radicals with α- or β-phosphorus substituents: (EtO)2P(O)CHCH2Mu and H2CCH(Mu)P(O)(OEt)2
- 1. Leicester Univ. (UK). Dept. of Chemistry
- 2. Rutherford Appleton Lab., Chilton (UK)
- 3. Zurich Univ. (Switzerland). Physikalisch-Chemisches Inst.
Description
The magnitudes of the muon-electron hyperfine coupling constants for the title radicals show that the muonium atom favours the out-of-plane site for the α-P substituted radical, but is constrained towards the in-plane site for the β-P substituted radical. (author)
Additional details
Publishing Information
- Journal Title
- J. Chem. Soc., Chem. Commun.
- Journal Issue
- no.6
- Series
- J. Chem. Soc., Chem. Commun.
- ISSN
- 0022-4936
- CODEN
- JCCCA
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 18074552
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ALKYL RADICALS; COUPLING CONSTANTS; ISOTOPE EFFECTS; MUONIUM; PHOSPHORUS; STRUCTURAL CHEMICAL ANALYSIS
- Descriptors DEC
- ELEMENTS; NONMETALS; RADICALS