Published March 2010 | Version v1
Journal article

Hooke's law correlation in two-electron systems

  • 1. Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory 0200 (Australia)

Description

We study the properties of the Hooke's law correlation energy (Ec), defined as the correlation energy when two electrons interact via a harmonic potential in a D-dimensional space. More precisely, we investigate the 1S ground-state properties of two model systems: the Moshinsky atom (in which the electrons move in a quadratic potential) and the spherium model (in which they move on the surface of a sphere). A comparison with their Coulombic counterparts is made that highlights the main differences of the Ec in both the weakly and strongly correlated limits. Moreover, we show that the Schroedinger equation of the spherium model is exactly solvable for two values of the dimension (D=1 and 3) and that the exact wave function is based on Mathieu functions.

Additional details

Publishing Information

Journal Title
Physical Review. A
Journal Volume
81
Journal Issue
3
Journal Page Range
p. 032510-032510.6
ISSN
1050-2947
CODEN
PLRAAN

Optional Information

Notes
(c) 2010 The American Physical Society