Hooke's law correlation in two-electron systems
Creators
- 1. Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory 0200 (Australia)
Description
We study the properties of the Hooke's law correlation energy (Ec), defined as the correlation energy when two electrons interact via a harmonic potential in a D-dimensional space. More precisely, we investigate the 1S ground-state properties of two model systems: the Moshinsky atom (in which the electrons move in a quadratic potential) and the spherium model (in which they move on the surface of a sphere). A comparison with their Coulombic counterparts is made that highlights the main differences of the Ec in both the weakly and strongly correlated limits. Moreover, we show that the Schroedinger equation of the spherium model is exactly solvable for two values of the dimension (D=1 and 3) and that the exact wave function is based on Mathieu functions.
Additional details
Identifiers
- DOI
- 10.1103/PhysRevA.81.032510;
- arXiv
- arXiv:1002.3396v2;
Publishing Information
- Journal Title
- Physical Review. A
- Journal Volume
- 81
- Journal Issue
- 3
- Journal Page Range
- p. 032510-032510.6
- ISSN
- 1050-2947
- CODEN
- PLRAAN
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 42001577
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ATOMS; COMPARATIVE EVALUATIONS; ELECTRON CORRELATION; ELECTRONS; EXACT SOLUTIONS; GROUND STATES; HARMONIC POTENTIAL; SCHROEDINGER EQUATION; SPACE; WAVE FUNCTIONS
- Descriptors DEC
- CORRELATIONS; DIFFERENTIAL EQUATIONS; ELEMENTARY PARTICLES; ENERGY LEVELS; EQUATIONS; EVALUATION; FERMIONS; FUNCTIONS; LEPTONS; MATHEMATICAL SOLUTIONS; NUCLEAR POTENTIAL; PARTIAL DIFFERENTIAL EQUATIONS; POTENTIALS; WAVE EQUATIONS
Optional Information
- Notes
- (c) 2010 The American Physical Society