Published September 13, 2021 | Version v1
Journal article Metadata-only

A neutral beryllium(I) radical

Creators

  • 1. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Würzburg, 97074 (Germany)
  • 2. Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Würzburg, 97074 (Germany)

Description

The reduction of a cyclic alkyl(amino)carbene (CAAC)-stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, and UV/Vis spectroscopy, X-ray crystallography, and DFT calculations. (© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH)

Additional details

Identifiers

DOI
10.1002/anie.202108405;

Publishing Information

Journal Title
Angewandte Chemie (International Edition)
Journal Volume
60
Journal Issue
38
Journal Page Range
p. 20776-20780
ISSN
1433-7851
CODEN
ACIEF5

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
52098589
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BERYLLIUM COMPOUNDS; CARBENES; DENSITY FUNCTIONAL METHOD; ELECTRON SPIN RESONANCE; INFRARED SPECTRA; ORGANOMETALLIC COMPOUNDS; RADICALS; SYNTHESIS; ULTRAVIOLET SPECTRA; X-RAY DIFFRACTION
Descriptors DEC
ALKALINE EARTH METAL COMPOUNDS; CALCULATION METHODS; COHERENT SCATTERING; DIFFRACTION; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; RADICALS; RESONANCE; SCATTERING; SPECTRA; VARIATIONAL METHODS