Published July 2008 | Version v1
Journal article Metadata-only

Optimization of the conditions of oxidation gas generation for determining chlorine, bromine, and iodine in aqueous solutions by inductively coupled plasma atomic-emission spectrometry

Creators

  • 1. SO RAN, Inst. Neorganicheskoj Khimii im. A.V. Nikolaeva, Novosibirsk (Russian Federation)
  • 2. Graz Univ. of Technology, Graz (Austria)

Description

A procedure is optimized for the gas generation of chlorine, bromine, and iodine by oxidation chloride, bromide, and iodide in solutions. The effect some oxidants (K2S2O8, H2O2, KMnO4, K2Cr2O7, NaNO2, KBrO3, KClO3, and KIO3) on the analytical signals of halogens in the short-wave spectral region, Cl(I) 134.724, Br(I) 154.065, and I(I) 178.276 nm is studied. A highly sensitive procedure is developed for determining chlorine, bromine, and iodine in aqueous solutions by inductively connected plasma atomic-emission spectrometry using the gas generation of halogens

Abstract (Russian)

Оптимизирована процедура газовой генерации хлора, брома и иода методом окисления хлорида, бромида и иодида из растворов. Исследовано действие ряда окислительных агентов (K2S2O8, Н2О2, KMnO4, K2Cr2O7, NaNO2, KBrO3, KClO3 и KIO3) на величины аналитических сигналов галогенов в коротковолновой области спектра - Сl(I) 134.724, Br(I) 154.065 и I(I) 178.276. Разработана высокочувствительная методика определения хлора, брома и иода в водных растворах методом атомно-эмиссионной спектрометрии с индуктивно связанной плазмой с применением газовой генерации галогенов

Additional details

Additional titles

Original title (Russian)
Optimizatsiya uslovij okislitel'noj gazovoj generatsii dlya opredeleniya khlora, broma i ioda v vodnykh rastvorakh metodom atomno-ehmissionnoj spektrometrii s induktivno svyazannoj plazmoj

Publishing Information

Journal Title
Zhurnal Analiticheskoj Khimii
Journal Volume
63
Journal Issue
7
Journal Page Range
p. 705-710
ISSN
0044-4502
CODEN
ZAKHA8

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
40088733
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACCURACY; AQUEOUS SOLUTIONS; EMISSION SPECTROSCOPY; IODIDES; IODINE; OPTIMIZATION; OXIDATION; QUANTITATIVE CHEMICAL ANALYSIS; SAMPLE PREPARATION; SENSITIVITY
Descriptors DEC
CHEMICAL ANALYSIS; CHEMICAL REACTIONS; DISPERSIONS; ELEMENTS; HALIDES; HALOGEN COMPOUNDS; HALOGENS; HOMOGENEOUS MIXTURES; IODINE COMPOUNDS; MIXTURES; NONMETALS; SOLUTIONS; SPECTROSCOPY

Optional Information

Notes
18 refs., 4 figs., 6 tabs.