Published 1977
| Version v1
Report
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Investigation into radiation stability of organic fluoro-chlorine compounds
Description
On the basis of a study of unmixed radiolysis of two-phase systems: CCl2FCF2OCCl3, 30% TBP + 70% CCl2FCF2OCCl3, 30% TBP + 70% C6Cl3F3, contacted with 4N HNO3, a linear relationship between chlorine ion accumulation and radiation dose magnitude has been established. However, fluorine ion accumulation is nonlinear. Trifluorotrichlorobenzene has been found to be the most stable of the compounds tested. The effect of radiolysis on the emulsion stratification rate has been considered for an emulsion formed by an extraction mixture of 30% TBP + 70% solvent in contact with an alkali or acid. It has been found that for the systems investigated the stratification rate decreases as the irradiation dose is increased
Availability note (English)
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9378548.pdf
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Additional details
Additional titles
- Original title (Russian)
- Исследование радиационной стойкости фторхлорорганических соединений
Publishing Information
- Imprint Pagination
- 26 p.
- Report number
- RI--58
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 9378548
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL REACTION KINETICS; GAMMA RADIATION; NITRIC ACID; ORGANIC CHLORINE COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; RADIATION DOSES; RADIOLYSIS; STABILITY; TBP
- Descriptors DEC
- BUTYL PHOSPHATES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; ESTERS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; IONIZING RADIATIONS; KINETICS; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORIC ACID ESTERS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS
Optional Information
- Notes
- 14 refs.; 7 figs.; 6 tables.