Published November 1991 | Version v1
Journal article Metadata-only

Kinetic regularities of oxygen-containing adducts formation in reaction of different-valence vanadium complexes interaction

Creators

  • 1. AN SSSR, Moscow (USSR). Inst. Khimicheskoj Fiziki

Description

A previously unknown property of vanadium peroxocomplexes VO(O2)pic·2Y2O (pic - picolinic acid) to react with vanadium complexes at high rates was revealed. Bimolecular rate constants of the reaction were determined. Totality of kinetic data points to formation of an adduct having peroxodimeric structure of different valency forms of vanadium. The adduct mentioned possesses a high activity in reactions of one-electron oxidation of ionol and its phenoxy radical

Additional details

Additional titles

Original title (Russian)
Кинетические закономерности образования кислородсодержащих аддуктов в реакции взаимодействия разновалентных комплексов ванадия

Publishing Information

Journal Title
Kinetika i Kataliz
Journal Volume
32
Journal Issue
6
Series
Kinet. Katal.
Journal Page Range
1310-1316
ISSN
0453-8811
CODEN
KNKTA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
23041529
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ADDUCTS; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; HYDRATES; MOLECULAR STRUCTURE; PEROXIDES; PICOLINIC ACID; VALENCE; VANADIUM COMPLEXES
Descriptors DEC
AZINES; CARBOXYLIC ACIDS; COMPLEXES; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; KINETICS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PICOLINES; PYRIDINES; REACTION KINETICS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES