Composition and photoelectrochemical properties of WO3/TNAs photoelectrodes fabricated by in situ electrochemical method
- 1. College of Resource and Environment, Qingdao Agricultural University, Changcheng Road 700, Chengyang District, Qingdao 266109 (China)
- 2. State Key Laboratory of Urban Water Resources and Environment (SKLUWRE), Department of Environmental Science and Engineering Harbin Institute of Technology, Huanghe Road 73, Nangang District, Harbin 150090 (China)
- 3. College of Science and Information, Qingdao Agricultura1 University, Changcheng Road 700, Chengyang District, Qingdao 266109 (China)
Description
TiO2/Ti Nanotube arrays (TNAs) and WO3/TNAs photoelectrodes were fabricated by in situ anodization and cycle pulse electrochemical deposition method. The morphology and structure were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectra and X-ray photoelectron spectroscopy (XPS). Optical properties and photoelectrochemical (PECH) properties were investigated by surface photovoltage (SPV), ultra UV–vis diffuse reflectance spectra (UV/vis/DRS), open-circuit potential (OCP), and photocurrent density The results showed that WO3/TNAs photoelectrodes have excellent photoresponse performance. WO3 would enhance the photovoltage and photocurrent of TNAs photoelectrodes. The presence of WO3 caused red shift and enhanced the photosensitivity of TNAs photoelectrodes in whole light region
Availability note (English)
Available from http://dx.doi.org/10.1016/j.electacta.2013.04.129Additional details
Identifiers
- DOI
- 10.1016/j.electacta.2013.04.129;
- PII
- S0013-4686(13)00836-0;
Publishing Information
- Journal Title
- Electrochimica Acta
- Journal Volume
- 104
- Journal Page Range
- p. 308-313
- ISSN
- 0013-4686
- CODEN
- ELCAAV
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 45052944
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AMINES; ANODIZATION; CHELATING AGENTS; ELECTRODEPOSITION; NANOTUBES; OPTICAL PROPERTIES; PHOTOSENSITIVITY; PULSES; RAMAN SPECTRA; SCANNING ELECTRON MICROSCOPY; SURFACES; TITANIUM OXIDES; TUNGSTATES; TUNGSTEN OXIDES; X-RAY DIFFRACTION; X-RAY PHOTOELECTRON SPECTROSCOPY
- Descriptors DEC
- CHALCOGENIDES; CHEMICAL COATING; COHERENT SCATTERING; CORROSION PROTECTION; DEPOSITION; DIFFRACTION; ELECTROCHEMICAL COATING; ELECTROLYSIS; ELECTRON MICROSCOPY; ELECTRON SPECTROSCOPY; LYSIS; MICROSCOPY; NANOSTRUCTURES; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHOTOELECTRON SPECTROSCOPY; PHYSICAL PROPERTIES; REFRACTORY METAL COMPOUNDS; SCATTERING; SENSITIVITY; SPECTRA; SPECTROSCOPY; SURFACE COATING; TITANIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; TUNGSTEN COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.