Published November 1, 1983
| Version v1
Journal article
Local mode theory for C/sub 3v/ molecules: CH3D, CHD3, SiH3D, and SiHD3
Creators
- 1. Theoretical Chemistry Department, 1 South Parks Road, Oxford OX1 3TG, England
Description
A three parameter potential model for the stretching vibrations of AH3D and AHD3 species (A = C or Si) is shown to give good agreement with experimental data thereby justifying predictions for the term values of unobserved levels. The structures of the overtone manifolds for different molecules are rationalized by means of an AH3 local mode to normal mode correlation diagram
Additional details
Publishing Information
- Journal Title
- J. Chem. Phys.
- Journal Volume
- 79
- Journal Issue
- 9
- Series
- J. Chem. Phys.
- Journal Page Range
- 4355-4362
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 15008638
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- DEUTERIUM; ISOTOPE EFFECTS; METHANE; OSCILLATION MODES; SILANES; VIBRATIONAL STATES
- Descriptors DEC
- ALKANES; ENERGY LEVELS; EXCITED STATES; HYDRIDES; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; SILICON COMPOUNDS; STABLE ISOTOPES