Published June 15, 1973 | Version v1
Journal article Metadata-only

Kinetic study of electronically excited phosphorus atoms, P(32D/sub J/,32P/sub J/), by atomic absorption spectroscopy. II

Creators

Description

Electronically excited phosphorus atoms in the P(32DJ) and P(32PJ) states have been generated in the gas phase by pulsed photolytic irradiation and monitored by means of absorption spectroscopy using attenuation of atomic resonance radiation. The kinetic decay of these two low-lying, optically metastable states has been studied in the presence of the following collision partners: Ar, Kr, Xe, N2, CO, NO, Co2, N2O, PCl3, CH4, and C2H4, and second-order constants are reported for the removal processes at 300°K.

Additional details

Identifiers

DOI
10.1063/1.1679140;

Publishing Information

Journal Title
The Journal of Chemical Physics
Journal Volume
58
Journal Issue
12
Series
J. Chem. Phys.
Journal Page Range
5272-5279
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
5095078
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ABSORPTION SPECTROSCOPY; ARGON; CARBON DIOXIDE; CARBON MONOXIDE; COLLISIONS; DE-EXCITATION; ETHYLENE; EXCITED STATES; KRYPTON; LIFETIME; METASTABLE STATES; METHANE; MOLECULE COLLISIONS; NITROGEN; NITROGEN OXIDES; PHOSPHORUS; PHOSPHORUS CHLORIDES; XENON
Descriptors DEC
ALKANES; ALKENES; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHLORIDES; CHLORINE COMPOUNDS; ELEMENTS; ENERGY LEVELS; ENERGY-LEVEL TRANSITIONS; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; NITROGEN COMPOUNDS; NONMETALS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; RARE GASES; SPECTROSCOPY

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