Published December 2016 | Version v1
Journal article

Thermophysical characterization of 1-ethylpyridinium triflate and comparison with similar ionic liquids

  • 1. Departamento de Química Física, Facultad de Ciencias, Universidad de Zaragoza, C/Pedro Cerbuna 12, 50009 Zaragoza (Spain)
  • 2. Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, C/María de Luna 3, 50018 Zaragoza (Spain)

Description

Highlights: • A thermophysical characterization of 1-ethylpyridinium triflate is presented. • The properties have been correlated with temperature. • The density at T = 303.15 K at several pressures has been also measured. • This study includes the thermal properties around the normal melting point. • A comparison with similar ionic liquids has been established. - Abstract: We present here a comprehensive thermophysical study of the piridynium-based ionic liquid: 1-ethylpyridinium triflate. Density, speed of sound, refractive index, surface tension, isobaric molar heat capacity, kinematic viscosity and electrical conductivity have been determined in the temperature range (293.15–338.15 K) and at pressure of 0.1 MPa, density was also measured in the pressure range (0.1–40 MPa) at T = 303.15 K. From these values, some derived properties have been calculated. In addition the thermal behaviour around the melting point has been registered. All these properties have been discussed and compared with those of two similar ionic liquids, 1-ethylpyridinium bis(trifluoromethylsulfonyl)imide and 1-butylpyridinium triflate.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2016.08.038

Additional details

Identifiers

DOI
10.1016/j.jct.2016.08.038;
PII
S0021-9614(16)30248-8;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
103
Journal Page Range
p. 395-402
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.