Thermophysical characterization of 1-ethylpyridinium triflate and comparison with similar ionic liquids
- 1. Departamento de Química Física, Facultad de Ciencias, Universidad de Zaragoza, C/Pedro Cerbuna 12, 50009 Zaragoza (Spain)
- 2. Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, C/María de Luna 3, 50018 Zaragoza (Spain)
Description
Highlights: • A thermophysical characterization of 1-ethylpyridinium triflate is presented. • The properties have been correlated with temperature. • The density at T = 303.15 K at several pressures has been also measured. • This study includes the thermal properties around the normal melting point. • A comparison with similar ionic liquids has been established. - Abstract: We present here a comprehensive thermophysical study of the piridynium-based ionic liquid: 1-ethylpyridinium triflate. Density, speed of sound, refractive index, surface tension, isobaric molar heat capacity, kinematic viscosity and electrical conductivity have been determined in the temperature range (293.15–338.15 K) and at pressure of 0.1 MPa, density was also measured in the pressure range (0.1–40 MPa) at T = 303.15 K. From these values, some derived properties have been calculated. In addition the thermal behaviour around the melting point has been registered. All these properties have been discussed and compared with those of two similar ionic liquids, 1-ethylpyridinium bis(trifluoromethylsulfonyl)imide and 1-butylpyridinium triflate.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2016.08.038Additional details
Identifiers
- DOI
- 10.1016/j.jct.2016.08.038;
- PII
- S0021-9614(16)30248-8;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 103
- Journal Page Range
- p. 395-402
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 49002175
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- DENSITY; ELECTRIC CONDUCTIVITY; EXPERIMENTAL DATA; MELTING POINTS; MOLTEN SALTS; ORGANIC FLUORINE COMPOUNDS; PYRIDINIUM COMPOUNDS; REFRACTIVE INDEX; SPECIFIC HEAT; SULFONATES; SURFACE TENSION; TEMPERATURE RANGE 0273-0400 K
- Descriptors DEC
- AMMONIUM COMPOUNDS; AZINES; DATA; ELECTRICAL PROPERTIES; HETEROCYCLIC COMPOUNDS; INFORMATION; NUMERICAL DATA; OPTICAL PROPERTIES; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHYSICAL PROPERTIES; PYRIDINES; QUATERNARY AMMONIUM COMPOUNDS; SALTS; SURFACE PROPERTIES; TEMPERATURE RANGE; THERMODYNAMIC PROPERTIES; TRANSITION TEMPERATURE
Optional Information
- Copyright
- Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.