Published October 1991 | Version v1
Journal article

Intermediate and metastable phases during synthesis of some lanthanide phosphates

  • 1. AN SSSR, Moscow (USSR). Inst. Obshchej i Neorganicheskoj Khimii

Description

The influence of ratio of interacting initial lanthanide (Ln=La-Eu) oxides and monoammonium phosphate during solid phase synthesis on the composition and structure of the phases formed was studied. The synthesis of oxophosphate Ln7P3O18 (7:3), the final temperature of the synthesis being 1400 deg C, in the temperature range of 1100-1200 deg C takes place via formation of Ln3PO7 oxophosphate intermediate phase, and La3PO7 oxophosphate is crystallized in metastable form, characteristic of stable modifications of Pr3PO7-Eu3PO7 series

Additional details

Additional titles

Original title (Russian)
Промежуточные и метастабильные фазы при синтезе некоторых фосфатов лантанидов
Augmented title (English)
La-Eu

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
36
Journal Issue
10
Series
Zh. Neorg. Khim.
Journal Page Range
2467-2469
ISSN
0044-457X
CODEN
ZNOKA