Insights into the photocatalysis mechanism of the novel 2D/3D Z-Scheme g-C3N4/SnS2 heterojunction photocatalysts with excellent photocatalytic performances

Highlights: • g-C₃N₄/SnS₂ shows superior photocatalytic activity for the removal of Cr⁶⁺ and BPS. • The photocatalytic degradation pathway of BPS is proposed based on the result of GC–MS. • DFT displays the band distribution of g-C₃N₄/SnS₂ is staggered near the forbidden. • Z-scheme photocatalysis mechanism is proposed based on the results of experiments and simulations. A novel 2D/3D Z-scheme g-C₃N₄/SnS₂ photocatalyst was successfully fabricated via self-assembly forming 3D flower-like SnS₂ microspheres on the surface of the 2D g-C₃N₄ nanosheets. The photocatalytic performances of the samples were systematically explored through catalytic reduction of Cr⁶⁺ and oxidation of Bisphenol S (BPS) under the illumination of visible light, and the photocatalytic degradation pathway of BPS was also proposed based on the degradation products confirmed by GCMS. Among the as-prepared samples, 0.4-g-C₃N₄/SnS₂ exhibited the most efficient photocatalytic performances, and the apparent quantum efficiency (QE) for the removal of Cr⁶⁺ could achieve 30.3 %, which is 2.8 times higher than that of the SnS₂. The enhancing photocatalytic activities originated from the efficient interfacial charge migration and separation obtained in g-C₃N₄/SnS₂, which was firstly verified via the photoluminescence spectra, time-resolved photoluminescence spectra and photoelectrochemical characterizations. Importantly, the DFT calculated shows that the band distribution of the g-C₃N₄/SnS₂ sample is staggered near the forbidden, which can facilitate the efficient interfacial charge migration and separation as well as result in the improvement of the catalytic activity. Finally, we put forward a more reasonable Z-scheme charge transfer mechanism, it was verified by analysing the results of free radical scavenging tests, EPR experiments and theoretical calculations.