Published January 2003 | Version v1
Journal article Metadata-only

Synthesis and structure of metal complexes of 1-(1-R-3-methylpyrazole-5-onylidene-4)-1,2,3,4-tetrahydroisoquinoline derivatives

Creators

  • 1. Inst. Tekhnicheskij Khimii UrO RAN, Perm' (Russian Federation)
  • 2. Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova RAN, Moscow (Russian Federation)
  • 3. Rossijskij Univ. Druzhby Narodov, Moscow (Russian Federation)

Description

Complex CdLI2 was prepared by interaction between cadmium iodide and spiro{cyclohexane-1,3'-[1-(1-phenyl-3-methylpyrazole-5-onylidene-4)-1,2,3,- te= trahydroisoquinoline]} (L) in acetone solution at room temperature with subsequent crystallization during 2-7 days. The product was characterized using elementary analysis. The structure of the cadmium complex prepared was discussed on the basis of CdLI2 absorption spectra in IR, UV and visible ranges, as well as relying on the results of previously conducted X-ray diffraction analysis of a copper complex with the same ligand (L)

Abstract (Russian)

Взаимодействием иодида кадмия с спиро{циклогексан-1,3'-[1-(1-фенил-3-метилпиразол-5-онилиден-4)-1,2,3,4 -тетраг = идроизохинолином]} (L) в растворе ацетона при комнатной температуре с последующей кристаллизацией в течение 2-7 суток получен комплекс CdLI2. Продукт охарактеризован с помощью элементного анализа. На основе спектров поглощения CdLI2 в ИК, УФ и видимой областях, а также результатов проведенного ранее рентгеноструктурного анализа комплекса меди с тем же лигандом (L), обсуждается строение полученного комплекса кадмия

Additional details

Additional titles

Original title (Russian)
Синтез и строение металлокомплексов производных 1-(1-Р-3-метилпиразол-5-онилиден-4)-1,2,3,4-тетрагидроизохинолина

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
29
Journal Issue
1
Journal Page Range
p. 18-23
ISSN
0132-344X
CODEN
KOKHDC

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
35043203
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; CADMIUM COMPLEXES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; INFRARED SPECTRA; IODIDES; MOLECULAR STRUCTURE; ORGANIC OXYGEN COMPOUNDS; PYRAZOLES; QUINOLINES
Descriptors DEC
AROMATICS; AZAARENES; AZINES; AZOLES; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; IODINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PYRIDINES; SPECTRA; SYNTHESIS

Optional Information

Notes
15 refs., 2 tabs.