Published March 2010 | Version v1
Report Restricted

Thermodynamic data of compounds and complexes of metal elements with organic ligands for JAEA-TDB

  • 1. Japan Atomic Energy Agency, Geological Isolation Research and Development Directorate, Tokai, Ibaraki (Japan)

Description

The thermodynamic database is used to evaluate solubility-limiting values of radio-nuclides in various types of groundwater for safety assessment of geological disposal for high-level radioactive waste and TRU waste. It is planned that JAEA-TDB has been developed modifying JNC-TDB released in 1999 by the end of FYJ 2009. The JAEA-TDB is planned to include thermodynamic data of compounds and complexes of metal elements with organic ligands which were not included in JNC-TDB. This report shows the selected thermodynamic data of compounds and complexes of metal elements with organic ligands which might be included in TRU waste in JAEA-TDB. Selected organics are oxalic acid, citric acid, ethylenediaminetetraacetic acid (EDTA) and iso-saccharinic acid (ISA) which were of interest in the OECD/NEA. The thermodynamic data evaluated by OECD/NEA were selected for JAEA-TDB. However, selected values by OECD/NEA are limited to evaluate the solubility calculation of radio-nuclides. Therefore, other published values and estimated values by LFER, Liner free energy relationship, are also selected as tentative values for JAEA-TDB. (author)

Availability note (English)

Available from JAEA; DOI: https://doi.org/10.11484/jaea-review-2009-060

Files

Restricted

The record is publicly accessible, but files are restricted to users with access.

System files (79.6 kB)

Name Size Download all

Additional details

Publishing Information

Imprint Pagination
36 p.
Report number
JAEA-Review--2009-060

Optional Information

Notes
29 refs., 8 figs., 20 tabs.