Pulsed adiabatic photoassociation via scattering resonances

We develop the theory for the adiabatic Raman photoassociation (ARPA) of ultracold atoms to form ultracold molecules in the presence of scattering resonances. Based on a computational method in which we replace the continuum with a discrete set of 'effective modes', we show that the existence of resonances greatly aids in the formation of deeply bound molecular states. We illustrate our general theory by computationally studying the formation of 85Rb2 molecules from pairs of colliding ultracold 85Rb atoms. The single-event transfer yield is shown to have a near-unity value for wide resonances, while the ensemble-averaged transfer yield is shown to be higher for narrow resonances. The ARPA yields are compared with that of (the experimentally measured) 'Feshbach molecule' magneto-association. Our findings suggest that an experimental investigation of ARPA at sub-μK temperatures is warranted.