Accidental degeneracy of the hydrogen atom and its non-accidental solution in parabolic coordinates
- 1. Dayananda Sagar University, Department of Physics, Bengaluru (India)
- 2. Indian Institute of Technology Tirupati, Department of Physics and CAMOST, Tirupati (India)
- 3. J.B.A.S. College for Women, Department of Physics, Chennai (India)
- 4. TCG Centers for Research and Education in Science and Technology, Kolkata (India)
- 5. Indian Institute of Technology Madras, Department of Physics, Chennai (India)
- 6. Indian Institute of Science Education and Research Mohali, Department of Physical Sciences, Mohali (India)
Description
The degeneracy associated with dynamical symmetry of a potential can be identified in quantum mechanics, by solving the Schrödinger equation analytically, using the method of separation of variables in at least two different coordinate systems, and in classical mechanics by solving the Hamilton–Jacobi equation. In the present pedagogical review, the notion of separability and superintegrability of a potential, with profound implications, is discussed. In an earlier tutorial paper, we addressed the n2-fold degeneracy of the hydrogen atom using the Casimir operators corresponding to the SO(4) symmetry of the 1/r potential. The present paper is a sequel to that work, in which we solve the Schrödinger equation for the hydrogen atom using separation of variables in the parabolic coordinate systems. In doing so, we take the opportunity to revisit some excellent works on symmetry and degeneracy in classical and quantum physics, if only to draw attention to these insightful studies, which unfortunately miss even a mention in most undergraduate and even graduate level courses in quantum mechanics and atomic physics. (author)
Availability note (English)
Available from DOI: https://doi.org/10.1139/cjp-2020-0258Additional details
Identifiers
Publishing Information
- Journal Title
- Canadian Journal of Physics
- Journal Volume
- 99
- Journal Issue
- 10
- Journal Page Range
- p. 853-860
- ISSN
- 0008-4204
INIS
- Country of Publication
- Canada
- Country of Input or Organization
- Canada
- INIS RN
- 53059728
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- CASIMIR OPERATORS; ELECTRIC POTENTIAL; HAMILTON-JACOBI EQUATIONS; HYDROGEN; SCHROEDINGER EQUATION; SYMMETRY GROUPS
- Descriptors DEC
- DIFFERENTIAL EQUATIONS; ELEMENTS; EQUATIONS; MATHEMATICAL OPERATORS; NONMETALS; PARTIAL DIFFERENTIAL EQUATIONS; WAVE EQUATIONS
Optional Information
- Notes
- 44 refs, 1 tab.