Published October 2021 | Version v1
Journal article

Accidental degeneracy of the hydrogen atom and its non-accidental solution in parabolic coordinates

  • 1. Dayananda Sagar University, Department of Physics, Bengaluru (India)
  • 2. Indian Institute of Technology Tirupati, Department of Physics and CAMOST, Tirupati (India)
  • 3. J.B.A.S. College for Women, Department of Physics, Chennai (India)
  • 4. TCG Centers for Research and Education in Science and Technology, Kolkata (India)
  • 5. Indian Institute of Technology Madras, Department of Physics, Chennai (India)
  • 6. Indian Institute of Science Education and Research Mohali, Department of Physical Sciences, Mohali (India)

Description

The degeneracy associated with dynamical symmetry of a potential can be identified in quantum mechanics, by solving the Schrödinger equation analytically, using the method of separation of variables in at least two different coordinate systems, and in classical mechanics by solving the Hamilton–Jacobi equation. In the present pedagogical review, the notion of separability and superintegrability of a potential, with profound implications, is discussed. In an earlier tutorial paper, we addressed the n2-fold degeneracy of the hydrogen atom using the Casimir operators corresponding to the SO(4) symmetry of the 1/r potential. The present paper is a sequel to that work, in which we solve the Schrödinger equation for the hydrogen atom using separation of variables in the parabolic coordinate systems. In doing so, we take the opportunity to revisit some excellent works on symmetry and degeneracy in classical and quantum physics, if only to draw attention to these insightful studies, which unfortunately miss even a mention in most undergraduate and even graduate level courses in quantum mechanics and atomic physics. (author)

Availability note (English)

Available from DOI: https://doi.org/10.1139/cjp-2020-0258

Additional details

Identifiers

Publishing Information

Journal Title
Canadian Journal of Physics
Journal Volume
99
Journal Issue
10
Journal Page Range
p. 853-860
ISSN
0008-4204

Optional Information

Notes
44 refs, 1 tab.