Published May 15, 1974
| Version v1
Journal article
Isotope effects on chemical equilibria. Part 2. Some further secondary isotope effects of the second kind
Creators
- 1. Memorial Univ. of Newfoundland, St. John's (Canada). Dept. of Chemistry
Description
The ratio of the dissociation constants K a (H)/K a (D) has been measured conductimetrically for the isotopic pairs XCH 2 COOH/XCD 2 COOH where X = Cl, PhO, and PhS. Methods of calculating the ratio of the equilibrium constants are considered in some detail. Since the isotope effect varies with the nature of the X substituent it is concluded that the simple inductive description of these effects is not tenable.
Additional details
Identifiers
- DOI
- 10.1139/v74-283;
Publishing Information
- Journal Title
- Canadian Journal of Chemistry
- Journal Volume
- 52
- Journal Issue
- 10
- Series
- Can. J. Chem.
- Journal Page Range
- 1966-1972
- ISSN
- 0008-4042
INIS
- Country of Publication
- Canada
- Country of Input or Organization
- Canada
- INIS RN
- 5145641
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CARBOXYLIC ACIDS; DEUTERIUM COMPOUNDS; DISSOCIATION; ISOTOPE EFFECTS; PH VALUE
- Descriptors DEC
- HYDROGEN COMPOUNDS; ORGANIC ACIDS; ORGANIC COMPOUNDS
Optional Information
- Notes
- 25 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent