Published July 1989 | Version v1
Journal article Metadata-only

Radiation polymerization of 2-hydroxy-3-butoxypropylacrylate and 2-hydroxy-3-tolylhydroxypropyl acrylate

Creators

  • 1. A.A. Zhdanov Leningrad State Univ. (USSR)

Description

The kinetics of γ-initiated bulk homopolymerization of 2-hydroxy-3-butoxypropyl acrylate and 2-hydroxy-3-tolylhydroxypropyl acrylate were studied by calorimetry. It was shown that the monomers are polymerized with high rates which are commensurate in the starting phase of the process when the character of kinetic chain breaking is close to bimolecular. With deep degrees of conversion, when the character of breaking approaches monomolecular, the rate of polymerization of 2-hydroxy-3-butoxypropyl acrylate is higher and it is polymerized to high degrees of conversion

Additional details

Publishing Information

Journal Title
High Energy Chemistry (English Translation)
Journal Volume
23
Journal Issue
1
Series
High Energy Chem. (Engl. Transl.).
Journal Page Range
19-21
ISSN
0018-1439
CODEN
HIECA

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
22033523
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Translation
Descriptors DEI
ACRYLIC ACID ESTERS; CALORIMETRY; CATALYSIS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; COBALT 60; COMPARATIVE EVALUATIONS; DOSE RATES; ESTERIFICATION; GAMMA RADIATION; IRON CHLORIDES; MONOMERS; ORGANIC POLYMERS; POLYMERIZATION; TEMPERATURE DEPENDENCE
Descriptors DEC
BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CARBOXYLIC ACID ESTERS; CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; COBALT ISOTOPES; ELECTROMAGNETIC RADIATION; ESTERS; EVALUATION; HALIDES; HALOGEN COMPOUNDS; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTO; IONIZING RADIATIONS; IRON COMPOUNDS; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; KINETICS; MINUTES LIVING RADIOISOTOPES; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; POLYMERS; RADIATION EFFECTS; RADIATIONS; RADIOISOTOPES; REACTION KINETICS; TRANSITION ELEMENT COMPOUNDS; YEARS LIVING RADIOISOTOPES

Optional Information

Notes
(English). Cover-to-cover Translation of Khimiya Vysokikh Energii (USSR). Cover-to-cover translation of Khimiya Vysokikh Ehnergij (USSR).