Published April 1, 1981 | Version v1
Journal article

The doublet structure of the DF-ODMR signals of triplet excitations in anthracene/TCNB

  • 1. Stuttgart Univ. (TH) (Germany, F.R.). Physikalisches Teilinstitut 3
  • 2. Ulm Univ. (Germany, F.R.). Abt. Theoretische Physik 1

Description

DF-ODMR signals (zero-field magnetic resonance detected by delayed fluorescence) of metastable triplet excitons in the 1:1 CT crystal anthracene/tetracyanobenzene are doublets with a splitting of 10 MHz. This structure is a consequence of Davydov splitting due to interchain exchange Jsub(b). The best fit gives Jsub(b) = 0.011 cm-1 and exciton zero-field splittings D = 2019.5, E = -248 MHz. (orig.)

Additional details

Publishing Information

Journal Title
Chem. Phys. Lett.
Journal Volume
79
Journal Issue
1
Series
Chem. Phys. Lett.
Journal Page Range
1-5
ISSN
0009-2614

INIS

Country of Publication
Netherlands
Country of Input or Organization
Netherlands
INIS RN
12628067
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ANTHRACENE; BENZENE; CHARGE-EXCHANGE REACTIONS; CYANIDES; ELECTRONIC STRUCTURE; ENERGY-LEVEL TRANSITIONS; EXCITONS; EXPERIMENTAL DATA; FLUORESCENCE; NMR SPECTRA; PHOSPHORESCENCE; TRIPLETS
Descriptors DEC
AROMATICS; CONDENSED AROMATICS; DATA; HYDROCARBONS; INFORMATION; LUMINESCENCE; MULTIPLETS; NUCLEAR REACTIONS; NUMERICAL DATA; ORGANIC COMPOUNDS; QUASI PARTICLES; SPECTRA