Published 1977 | Version v1
Journal article Metadata-only

γ-radiolysis of liquid pentanes. The role of positive ions in the formation of stable products in irradiated isopentane and n-pentane

Creators

  • 1. Institute of Nuclear Research, Warsaw (Poland)

Description

The influence of NH3 and C2H5OH on the stable product yields in γ-irradiated liquid isopentane and n-pentane has been investigated. Different scavenging efficiencies towards the ionic precursors of some light products in the two C(5) isomers have been found, and the relative reactivities of ethanol and ammonia have been calculated. A scheme describing the main ionic fragmentation reactions in isopentane and n-pentane has been proposed. (author)

Additional details

Identifiers

DOI
10.1016/0146-5724(77)90036-x;

Publishing Information

Journal Title
Radiation Physics and Chemistry (1977)
Journal Volume
10
Journal Issue
5-6
Series
Radiat. Phys. Chem.
Journal Page Range
309-314
ISSN
0020-7055

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
9365046
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
AMMONIA; CATIONS; CHEMICAL REACTION KINETICS; ETHANOL; G VALUE; GAMMA RADIATION; ISOMERS; PENTANE; RADICALS; RADIOLYSIS; SCAVENGING
Descriptors DEC
ALCOHOLS; ALKANES; CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; HYDRIDES; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; IONIZING RADIATIONS; IONS; KINETICS; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS

Optional Information

Notes
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