Published September 10, 1990 | Version v1
Journal article

Microstructure of Cu- and Y-rich YBa2Cu3O7-x thin films: Identification of the CuYO2 phase

  • 1. Stanford University, Stanford, CA (USA). Department of Applied Physics
  • 2. Stanford University, Stanford, CA (USA). Center for Materials Research

Description

The CuYO2 delafossite-type structure has been identified as a second phase in thin films of Cu- and Y-rich YBa2Cu3O7-x (123) made by electron beam co-evaporation at conditions of low oxygen pressure; this phase occurs as extremely small, densely distributed, highly oriented precipitates within the 123 matrix. The smallest (sub-100 A) [00.1] oriented precipitates of this hexagonal phase are strained to give a better lattice match to the surrounding 123 structure. The results suggest that, for thin film deposition conditions of sufficiently low temperature and pressure, there may be a tie line between YBa2Cu3O7-x and CuYO2 in the equilibrium phase diagram. The size and distribution of the precipitates is such as would be expected to influence structurally sensitive superconducting transport properties

Additional details

Publishing Information

Journal Title
Applied Physics Letters
Journal Volume
57
Journal Issue
11
Series
Appl. Phys. Lett.
Journal Page Range
1158-1160
ISSN
0003-6951
CODEN
APPLA