Published June 2006 | Version v1
Journal article Metadata-only

Reaction of aryl diazonium tetrafluoro borates with allyl methacrylate in the presence of rhodanide-anion

Creators

  • 1. Natsional'nyj Pedagogicheskij Univ. imeni Vladimira Gnatyuka, Ternopol' (Ukraine)

Description

Reaction of aryl diazonium tetrafluoro borates (I) with allyl ester of methacrylic acid in the water-acetone (1:5) medium is studied by means of IR spectroscopy and 1H NMR. It is established that (I) reacts with aryl methacrylate in the presence of rhodanide-anion and catalytic quantities of copper salts with the formation of allyl esters of 2-thiocyanato-2-methyl-3-aryl propionic acids with the yield of 32-56%. Allyl fragment of biunsaturated compound shows no reaction under the tested conditions

Abstract (Russian)

С помощью ИК-спектроскопии и ЯМР 1Н изучена реакция тетрафторборатов арилдиазония (I) с аллиловым эфиром метакриловой кислоты в водно-ацетоновой (1:5) среде. Установлено, что (I) взаимодействуют с арилметакрилатом в присутствии роданид-аниона и каталитических количеств солей меди с образованием аллиловых эфиров 2-тиоцианато-2-метил-3-арилпропионовых кислот с выходами 32-56%. В испытанных условиях аллильный фрагмент бинепредельного соединения в реакцию не вступает

Additional details

Additional titles

Original title (Russian)
Взаимодействие тетрафтороборатов арилдиазония с аллилметакрилатом в присуцтвии родианид-аниона

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
76
Journal Issue
6
Journal Page Range
p. 978-980
ISSN
0044-460X
CODEN
ZOKHA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
37104087
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ARYLATION; AZO COMPOUNDS; CHEMICAL COMPOSITION; INFRARED SPECTRA; METHACRYLIC ACID ESTERS; MONOCARBOXYLIC ACIDS; NUCLEAR MAGNETIC RESONANCE; ORGANIC BORON COMPOUNDS; THIOCYANATES
Descriptors DEC
ANTITHYROID DRUGS; CARBONIC ACID DERIVATIVES; CARBOXYLIC ACID ESTERS; CARBOXYLIC ACIDS; CHEMICAL REACTIONS; DRUGS; ESTERS; MAGNETIC RESONANCE; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; RESONANCE; SPECTRA

Optional Information

Notes
10 refs., 2 tabs.