Published March 1, 2009 | Version v1
Journal article

Observation of two elastic thresholds in GexAsySe1-x-y glasses

  • 1. Centre for Ultrahigh Bandwidth Devices for Optical Systems (CUDOS), Laser Physics Centre, Research School of Physics and Engineering, Australian National University, Canberra, ACT 0200 (Australia)
  • 2. Research School of Earth Sciences, Australian National University, Canberra, ACT 0200 (Australia)

Description

We have prepared GexAsySe1-x-y glasses with mean coordination numbers (MCNs) from 2.2 to 2.86. Tg was found to generally increase with increasing MCN while the glass density showed a maximum at MCN≅2.45 and a minimum at MCN≅2.65. The elastic moduli of the glasses were estimated from the shear and compressional wave velocities measured by ultrasonic pulse interferometry. For the first time we simultaneously observed two elastic transition thresholds, the first at MCN≅2.45 and the second at MCN≅2.65, which appear closely correlated with changes in the glass microstructure. The elastic moduli of two groups of samples with the same MCN=2.4 and 2.64 but different compositions suggest that the chemical compositions also have an influence on the elastic properties

Additional details

Identifiers

Publishing Information

Journal Title
Journal of Applied Physics
Journal Volume
105
Journal Issue
5
Journal Page Range
p. 056109-056109.3
ISSN
0021-8979
CODEN
JAPIAU

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
40062335
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
CHEMICAL COMPOSITION; GERMANIUM ARSENIDES; GERMANIUM SELENIDES; GLASS; INTERFEROMETRY; MICROSTRUCTURE; WAVE PROPAGATION
Descriptors DEC
ARSENIC COMPOUNDS; ARSENIDES; CHALCOGENIDES; GERMANIUM COMPOUNDS; PNICTIDES; SELENIDES; SELENIUM COMPOUNDS

Optional Information

Notes
(c) 2009 American Institute of Physics