Potential for developing independent daytime/nighttime LUR models based on short-term mobile monitoring to improve model performance

Highlights: • The land use regression models were developed based on mobile monitoring campaigns. • The strategy for daytime/nighttime independent modeling was evaluated in two periods. • Daytime/nighttime models (PM_2.5 and PM₁₀) performed better than the full-day models. • Exposure surfaces revealed variations in concentrations and spatial distribution. Land use regression model (LUR) is a widespread method for predicting air pollution exposure. Few studies have explored the performance of independently developed daytime/nighttime LUR models. In this study, fine particulate matter (PM_2.5), inhalable particulate matter (PM₁₀), and nitrogen dioxide (NO₂) concentrations were measured by mobile monitoring during non-heating and heating seasons in Taiyuan. Pollutant concentrations were higher in the nighttime than the daytime, and higher in the heating season than the non-heating season. Daytime/nighttime and full-day LUR models were developed and validated for each pollutant to examine variations in model performance. Adjusted coefficients of determination (adjusted R²) for the LUR models ranged from 0.53–0.87 (PM_2.5), 0.53–0.85 (PM₁₀), and 0.33–0.67 (NO₂). The performance of the daytime/nighttime LUR models for PM_2.5 and PM₁₀ was better than that of the full-day models according to the results of model adjusted R² and validation R². Consistent results were confirmed in the non-heating and heating seasons. Effectiveness of developing independent daytime/nighttime models for NO₂ to improve performance was limited. Surfaces based on the daytime/nighttime models revealed variations in concentrations and spatial distribution. In conclusion, the independent development of daytime/nighttime LUR models for PM_2.5/PM₁₀ has the potential to replace full-day models for better model performance. The modeling strategy is consistent with the residential activity patterns and contributes to achieving reliable exposure predictions for PM_2.5 and PM₁₀. Nighttime could be a critical exposure period, due to high pollutant concentrations.