Published May 1975 | Version v1
Journal article Metadata-only

γ-radiolysis of an olefin-liquid carbon dioxide mixture

Creators

  • 1. Osaka Univ., Suita (Japan). Inst. of Scientific and Industrial Research

Description

Radiolysis of an aliphatic olefin(0.01 mol)-liq. CO2(1 mol) mixture has been investigated at room temperature. The main products were the corresponding epoxide and carbonyl compounds. A biradical intermediate which is formed by addition of oxygen atom to olefinic double bond is proposed. The nature of the oxidizing species is discussed. (auth.)

Additional details

Identifiers

DOI
10.1246/cl.1975.469;

Publishing Information

Journal Title
Chemistry Letters
Journal Volume
4
Journal Issue
5
Series
Chem. Lett. (Tokyo).
Journal Page Range
469-470
ISSN
0366-7022

INIS

Country of Publication
Japan
Country of Input or Organization
Japan
INIS RN
7248037
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
BUTENES; CARBON DIOXIDE; CHEMICAL REACTION KINETICS; GAMMA RADIATION; HEXENES; IRRADIATION; LIQUIDS; MASS SPECTROSCOPY; MIXTURES; OXIDATION; PENTENES; RADICALS; RADIOLYSIS
Descriptors DEC
ALKENES; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; DISPERSIONS; ELECTROMAGNETIC RADIATION; FLUIDS; HYDROCARBONS; IONIZING RADIATIONS; KINETICS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; SPECTROSCOPY

Optional Information

Notes
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