Dynamics and geometric properties of the k-trigonometric model
Creators
- 1. Dipartimento di Fisica and INFM, Universita di Roma La Sapienza, P A Moro 2, 00185 Rome (Italy)
- 2. Laboratoire de Physique Theorique, Ecole Normale Superieure, 24 Rue Lhomond, 75231 Paris Cedex 05 (France)
- 3. PMMH Ecole Superieure de Physique et Chimie Industrielles, 10 Rue Vauquelin, 75231 Paris Cedex 05 (France)
Description
We analyse the dynamics and the geometric properties of the potential energy surfaces (PES) of the k-trigonometric model (kTM), defined by a fully connected k-body interaction. This model has no thermodynamic transition for k = 1, a second-order one for k = 2, and a first-order one for k > 2. In this paper we (i) show that the single-particle dynamics can be traced back to an effective dynamical system (with only one degree of freedom), (ii) compute the diffusion constant analytically, (iii) determine analytically several properties of the self-correlation functions apart from the relaxation times which we calculate numerically, (iv) relate the collective correlation functions to those of the effective degree of freedom using an exact Dyson-like equation, (v) using two analytical methods, calculate the saddles of the PES that are visited by the system evolving at fixed temperature. On the one hand we minimize vertical bar ∇V vertical bar2, as usually done in the numerical study of supercooled liquids and, on the other hand, we compute the saddles with minimum distance (in configuration space) from initial equilibrium configurations. We find the same result from the two calculations and we speculate that the coincidence might go beyond the specific model investigated here
Availability note (English)
Available online at http://stacks.iop.org/0305-4470/36/8565/a33203.pdf or at the Web site for the Journal of Physics. A, Mathematical and General (ISSN 1361-6447) http://www.iop.org/Additional details
Identifiers
- URL
- http://stacks.iop.org/0305-4470/36/8565/a33203.pdf; http://www.iop.org/;
- DOI
- 10.1088/0305-4470/36/32/303;
- PII
- S0305-4470(03)62606-5;
Publishing Information
- Journal Title
- Journal of Physics. A, Mathematical and General
- Journal Volume
- 36
- Journal Issue
- 32
- Journal Page Range
- p. 8565-8601
- ISSN
- 0305-4470
- CODEN
- JPHAC5
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 35000293
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; S74: ATOMIC AND MOLECULAR PHYSICS; S36: MATERIALS SCIENCE;
- Descriptors DEI
- ANALYTICAL SOLUTION; CORRELATION FUNCTIONS; DEGREES OF FREEDOM; DIFFUSION EQUATIONS; DYSON REPRESENTATION; MATHEMATICAL MODELS; NUMERICAL SOLUTION; POTENTIAL ENERGY; RELAXATION TIME
- Descriptors DEC
- DIFFERENTIAL EQUATIONS; ENERGY; EQUATIONS; FUNCTIONS; MATHEMATICAL SOLUTIONS; PARTIAL DIFFERENTIAL EQUATIONS