Published December 14, 2012 | Version v1
Journal article

Co2SnO4/activated carbon composite electrode for supercapacitor

  • 1. State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, Sichuan (China)
  • 2. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan (China)

Description

A new kind of Co2SnO4-based electrode materials for supercapacitor was synthesized by co-precipitation method. The microstructure and surface morphology of Co2SnO4 were characterized by X-ray diffraction and scanning electron microscopy, respectively. Cyclic voltammetry, chronopotentiometry and electrochemical impedance spectroscopy were employed for the determination of specific capacitance and the equivalent series resistance of Co2SnO4/activated carbon composite electrode in KCl solution. It was shown that the composite electrode with 25 wt% Co2SnO4 had excellent specific capacitance up to 285.3 F g−1 at the current density of 5 mA cm−2. In addition, the composite electrode exhibited excellent long-term stability and, after 1000 cycles, 70.6% of initial capacitance was retained. Regarding the low cost, easy preparation, steady performance and environment friendliness, Co2SnO4/activated carbon composite electrode could have potentially promising application for supercapacitor. -- Highlights: ► Crystalline Co2SnO4 was synthesized by co-precipitation method. ► The specific capacitance of Co2SnO4/AC composite electrode was up to 285.3 F g−1. ► Co2SnO4/AC composite electrode showed excellent electrochemical reversibility. ► Co2SnO4/AC composite electrode showed long cycle life and high stability.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.matchemphys.2012.10.004

Additional details

Identifiers

DOI
10.1016/j.matchemphys.2012.10.004;
PII
S0254-0584(12)00865-6;

Publishing Information

Journal Title
Materials Chemistry and Physics
Journal Volume
137
Journal Issue
2
Journal Page Range
p. 576-579
ISSN
0254-0584
CODEN
MCHPDR

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
45027801
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ACTIVATED CARBON; COMPOSITE MATERIALS; MICROSTRUCTURE; SCANNING ELECTRON MICROSCOPY; STABILITY; X-RAY DIFFRACTION
Descriptors DEC
ADSORBENTS; CARBON; COHERENT SCATTERING; DIFFRACTION; ELECTRON MICROSCOPY; ELEMENTS; MATERIALS; MICROSCOPY; NONMETALS; SCATTERING

Optional Information

Copyright
Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.