Densities, refractive indices, and viscosities of N,N-diethylethanol ammonium chloride–glycerol or –ethylene glycol deep eutectic solvents and their aqueous solutions
- 1. R and D Center for Membrane Technology and Department of Chemical Engineering, Chung Yuan Christian University, Chung Li 32023, Taiwan, ROC (China)
- 2. School of Chemical Engineering and Chemistry, Mapúa Institute of Technology, Manila 1002 (Philippines)
Description
Highlights: • The densities, refractive indices, and viscosities of aqueous DES solutions were measured. • DES are made from N,N-diethylethanol ammonium chloride + glycerol or ethylene glycol. • The temperature studied was (298.15 to 343.15) K. • The measured data were reported as functions of temperature and composition. • The measured data were represented satisfactorily by the applied correlations. -- Abstract: In this work, we report new experimental data on density, ρ, refractive index, nD, and viscosity, η, of two deep eutectic solvents, N,N-diethylethanol ammonium chloride–glycerol (DEACG) and N,N-diethylethanol ammonium chloride–ethylene glycol (DEACEG), and their aqueous solutions, over the complete composition range, at temperatures from (298.15 to 343.15) K. Densities and viscosities were measured using the vibrating tube and the falling ball techniques, respectively, while the refractive index at the sodium D line was measured using an automatic refractometer. We aimed to represent the measured properties as a function of temperature and composition, and correlated them using the Redlich–Kister-type equation, for density, a polynomial function, for refractive index, and the Vogel–Fulcher–Tammann (VFT) equation, for viscosity
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2013.05.041Additional details
Identifiers
- DOI
- 10.1016/j.jct.2013.05.041;
- PII
- S0021-9614(13)00202-4;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 65
- Journal Page Range
- p. 65-72
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 45053535
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AMMONIUM CHLORIDES; AQUEOUS SOLUTIONS; DENSITY; EUTECTICS; GLYCEROL; GLYCOLS; POLYNOMIALS; REFRACTIVE INDEX; SOLVENTS; TEMPERATURE DEPENDENCE; VISCOSITY
- Descriptors DEC
- ALCOHOLS; AMMONIUM COMPOUNDS; AMMONIUM HALIDES; CHLORIDES; CHLORINE COMPOUNDS; DISPERSIONS; FUNCTIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROXY COMPOUNDS; MIXTURES; OPTICAL PROPERTIES; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; SOLUTIONS
Optional Information
- Copyright
- Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.