Published October 2013 | Version v1
Journal article

Densities, refractive indices, and viscosities of N,N-diethylethanol ammonium chloride–glycerol or –ethylene glycol deep eutectic solvents and their aqueous solutions

  • 1. R and D Center for Membrane Technology and Department of Chemical Engineering, Chung Yuan Christian University, Chung Li 32023, Taiwan, ROC (China)
  • 2. School of Chemical Engineering and Chemistry, Mapúa Institute of Technology, Manila 1002 (Philippines)

Description

Highlights: • The densities, refractive indices, and viscosities of aqueous DES solutions were measured. • DES are made from N,N-diethylethanol ammonium chloride + glycerol or ethylene glycol. • The temperature studied was (298.15 to 343.15) K. • The measured data were reported as functions of temperature and composition. • The measured data were represented satisfactorily by the applied correlations. -- Abstract: In this work, we report new experimental data on density, ρ, refractive index, nD, and viscosity, η, of two deep eutectic solvents, N,N-diethylethanol ammonium chloride–glycerol (DEACG) and N,N-diethylethanol ammonium chloride–ethylene glycol (DEACEG), and their aqueous solutions, over the complete composition range, at temperatures from (298.15 to 343.15) K. Densities and viscosities were measured using the vibrating tube and the falling ball techniques, respectively, while the refractive index at the sodium D line was measured using an automatic refractometer. We aimed to represent the measured properties as a function of temperature and composition, and correlated them using the Redlich–Kister-type equation, for density, a polynomial function, for refractive index, and the Vogel–Fulcher–Tammann (VFT) equation, for viscosity

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2013.05.041

Additional details

Identifiers

DOI
10.1016/j.jct.2013.05.041;
PII
S0021-9614(13)00202-4;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
65
Journal Page Range
p. 65-72
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.