Published January 1, 2014 | Version v1
Journal article

Simulation of lithium iron phosphate lithiation/delithiation: Limitations of the core–shell model

  • 1. Chemical Engineering Department, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L 3G1 (Canada)
  • 2. Vehicle Development Research Lab., GM R and D Center, MI 48090-9055 (United States)
  • 3. Electrical and Controls Intergration Lab., 30500 Mound Road, GM R and D, MI 48090 (United States)

Description

In this work the limitations in using the core–shell models to simulate the operation of lithium iron phosphate electrodes are discussed and analyzed. The complications arising from the stepwise nature of the core–shell model and erroneous predictions of this model for special conditions are detailed

Availability note (English)

Available from http://dx.doi.org/10.1016/j.electacta.2013.10.159

Additional details

Identifiers

DOI
10.1016/j.electacta.2013.10.159;
PII
S0013-4686(13)02129-4;

Publishing Information

Journal Title
Electrochimica Acta
Journal Volume
115
Journal Page Range
p. 352-357
ISSN
0013-4686
CODEN
ELCAAV

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
45059475
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ELECTRODES; FORECASTING; IRON PHOSPHATES; LITHIUM; SIMULATION
Descriptors DEC
ALKALI METALS; ELEMENTS; IRON COMPOUNDS; METALS; OXYGEN COMPOUNDS; PHOSPHATES; PHOSPHORUS COMPOUNDS; TRANSITION ELEMENT COMPOUNDS

Optional Information

Copyright
Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.